Related Products of 57196-62-0, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.57196-62-0, Name is 6-Methoxy-1,2,3,4-tetrahydroisoquinoline hydrochloride, molecular formula is C10H14ClNO. In a Article£¬once mentioned of 57196-62-0
Multimetallic complexes and functionalized nanoparticles based on oxygen- and nitrogen-donor combinations
The versatile precursors [Ru(CH=CHC6H4Me-4)Cl(CO) (BTD)(PPh3)2] (BTD = 2,1,3-benzothiadiazole) and [Ru(C(Ci – CPh)=CHPh)Cl(CO)(PPh3)2] were treated with isonicotinic acid, 4-cyanobenzoic acid, and 4-(4-pyridyl)benzoic acid under basic conditions to yield [Ru(vinyl)(O2CC5H 4N)(CO)(PPh3)2], [Ru(vinyl)(O 2CC6H4CN-4)(CO)(PPh3)2], and [Ru(vinyl){O2CC6H4(C5H 4N)-4}(CO)(PPh3)2], respectively. The osmium analogue [Os(CH=CHC6H4Me-4)(O2CC 5H4N)(CO)(PPh3)2] was also prepared. cis-[RuCl2(dppm)2] was used to prepare the cationic compounds [Ru(O2CC5H4N)(dppm)2] + and [Ru{O2CC6H4(C 5H4N)-4}(dppm)2]+. The treatment of 2 equiv of [Ru(C(Ci – CPh)=CHPh)(O2CC5H 4N)(CO)(PPh3)2] and [Ru(O2CC 5H4N)(dppm)2]+ with AgOTf led to the trimetallic compounds [{Ru(C(Ci – CPh)=CHPh)(CO)(PPh3) 2(O2CC5H4N)}2Ag] + and [{Ru(dppm)2(O2CC5H 4N)}2Ag]3+. In a similar manner, the reaction of [Ru(O2CC5H4N)(dppm)2]+ with PdCl2 or K2PtCl4 yielded [{Ru(dppm) 2(O2CC5H4N)}2MCl 2]2+ (M = Pd, Pt). The reaction of [RuHCl(CO)(BTD) (PPh3)2] with HCi – CC6H4F-4 provided [Ru(CH=CHC6H4F-4)Cl(CO)(BTD)(PPh 3)2], which was treated with isonicotinic acid and base to yield [Ru(CH=CHC6H4F-4)(O2CC5H 4N)(CO)(PPh3)2]. The addition of [Au(C 6F5)(tht)] (tht = tetrahydrothiophene) resulted in the formation of [Ru(CH=CHC6H4F-4){O2CC 5H4N(AuC6F5)}(CO)(PPh 3)2]. Similarly, [Ru(vinyl)(O2CC 6H4CN-4)(CO)(PPh3)2] reacted with [Au(C6F5)(tht)] to provide [Ru(vinyl){O2CC 6H4(CNAuC6F5)-4}(CO)(PPh 3)2]. The reaction of 4-cyanobenzoic acid with [Au(C 6F5)(tht)] yielded [Au(C6F5) (NCC6H4CO2H-4)]. This compound was used to prepare [Ru(CH=CHC6H4F-4){O2CC 6H4(CNAuC6F5)-4}(CO)(PPh 3)2], which was also formed on treatment of [Ru(CH=CHC6H4F-4)(O2CC6H 4CN-4)(CO)(PPh3)2] with [Au(C6F 5)(tht)]. The known compound [RhCl2(NC5H 4CO2)(NC5H4CO2Na) 3] and the new complex [RhCl2{NC5H 4(C6H4CO2)-4}{NC5H 4(C6H4CO2Na)-4}3] were prepared from RhCl3¡¤3H2O and isonicotinic acid or 4-(4-pyridyl)benzoic acid, respectively. The former was treated with [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3) 2] to yield [RhCl2{NC5H4CO 2(Ru(CH=CHC6H4Me-4)(CO)(PPh3) 2}4]Cl. As an alternative route to pentametallic compounds, the Pd-coordinated porphyrin [(Pd-TPP)(p-CO2H) 4] was treated with 4 equiv of [Ru(CH=CHR)Cl(CO)(BTD)(PPh 3)2] in the presence of a base to yield [(Pd-TPP){p-CO2Ru(CH=CHR)(CO)(PPh3)2} 4] (R = C6H4Me-4, CPh2OH). Where R = CPh2OH, treatment with HBF4 led to the formation of [(Pd-TPP){p-CO2Ru(=CHCH=CPh2)(CO)(PPh3) 2}4](BF4)4. [(Pd-TPP){p-CO 2Ru(dppm)2}4](PF6)4 was prepared from [(Pd-TPP)(p-CO2H)4] and cis-[RuCl 2(dppm)2]. The reaction of AgNO3 with sodium borohydride in the presence of [Ru(O2CC5H 4N)(dppm)2]+ or [RuR{O2CC 6H4(C5H4N)-4}(dppm) 2]+ provided silver nanoparticles Ag[NC5H 4CO2Ru(dppm)2]+ and Ag[NC 5H4{C6H4CO2Ru(dppm) 2}-4]+.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 57196-62-0
Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem