A new application about 2-Methyl-1,2,3,4-tetrahydroisoquinoline

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1612-65-3, Name is 2-Methyl-1,2,3,4-tetrahydroisoquinoline, belongs to tetrahydroisoquinoline compound, is a common compound. Quality Control of 2-Methyl-1,2,3,4-tetrahydroisoquinolineIn an article, once mentioned the new application about 1612-65-3.

Mild Reductive Cleavage of alpha-Aminoethers

1,2,3,4-Tetrahydro-6,7-dimethoxy-2-methylisoquinoline (1) is converted by ethyl chloroformate (ECF)/NaBH3CN to 2--4,5-dimethoxytoluene (4) via the quaternary urethane 2.The same procedure leads from laudanosine (5) to the dibenzyl derivative 9.The reaction with ECF/NaBH3CN followed by LiAlH4 reduction is a versatile approach to Emde degradation products avoiding strongly basic conditions and elevated temperature.Cleavage reactions of other alpha-amino ethers, e.g. thebaine (18), and N-demethylation reactions of thetetrahydroisoquinolines 1 and 10 with ECF are reported.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem