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Graphene-supported RuO2 nanoparticles for efficient aerobic cross-dehydrogenative coupling reaction in water
A cross-dehydrogenative coupling (CDC) reaction between tertiary amines and nitroalkanes has been realized under an oxygen atmosphere in water simply by using graphene-supported RuO2 as the catalyst, which was made from water-soluble graphene with sulfonic groups and RuCl3·nH 2O to form RuO2·nH2O nanocomposites in situ. In contrast to RuCl3·nH2O and RuO 2·nH2O, the graphene-supported RuO2 nanoparticles exhibited higher activity and stability for the aerobic CDC reaction in water.
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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem