Chemical Research Letters, May 2021. Electric Literature of 166591-85-1, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.166591-85-1, Name is 2-(tert-Butoxycarbonyl)-1,2,3,4-tetrahydroisoquinoline-1-carboxylic acid, molecular formula is C15H19NO4. In a Article,once mentioned of 166591-85-1
Stereoselective introduction of an alkoxy group to the amine unit of lactamide derivatives, under electrochemical oxidation conditions, was investigated based upon the assumption that a cyclic oxonium ion can be formed between the alkoxy substituent on the chiral center and a carbocation generated at the alpha-position of N-alkyl substituents. With N-monosubstituted lactamides, diastereoselectivity in the N-alpha-alkoxylated product was not observed. With N,N-disubstituted lactamides, however, the selectivity appeared though in low ratios (?2.2). Requisite factors that govern the stereoselectivity, i.e. nucleophilicity of both internal and external nucleophiles and substitution on amine units, were also examined.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 166591-85-1 is helpful to your research. Electric Literature of 166591-85-1
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem