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The invention concerns a method of modifying an epoxidised natural rubber that helps improve grafting performance. The method comprises: – reacting an epoxidised natural rubber with a system consisting of – a carboxylic acid of general formula (I) in which R represents a group likely to interact with a reinforcing filler and – an imidazole of general formula (II) in which, – R1 represents a hydrocarbon group or a hydrogen atom, – R2 represents a hydrocarbon group, R3 and R4 represent, independent of each other, a hydrogen atom or a hydrocarbon group, or indeed R3 and R4 form a ring together with the carbon atoms of the imidazole ring to which they bond, – then curing at a temperature greater than 120C.
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Reference：
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem