Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: cis-Dichlorobis(pyridine)platinum(II), is researched, Molecular C10H10Cl2N2Pt, CAS is 15227-42-6, about Research at ICI Central Petrochemical and Polymer Laboratory, Runcorn Heath. NQR spectrometry.Computed Properties of C10H10Cl2N2Pt.
The use of 35Cl nuclear quadrupole resonance (NQR) in the study of transition metal compounds is discussed. In the NQR spectra of cis-and trans-L2PtCl2, the difference in the 35Cl NQR frequencies (νtrans-νcis) increases 0.95, 1.98, 3.1 MHz, for L = Me2NH, pyridine, and Bu3P, resp. Frequency variation is greater among the trans compounds Charge donating properties of L to Pt have a larger effect on the ν 35 Cl attached to the Pt than does the weakening influence of L. The 35Clν for bridging Cl in trans-L2Pt2Cl4 and trans-L2Pd2Cl4 are much lower (at 15.46 and 12.84 MHz, resp.) than the frequencies of the terminal Cl(at 22.36 and 19.56 MHz). This difference can be used in studying cluster compounds
Here is a brief introduction to this compound(15227-42-6)Computed Properties of C10H10Cl2N2Pt, if you want to know about other compounds related to this compound(15227-42-6), you can read my other articles.
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem