SDS of cas: 15227-42-6. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: cis-Dichlorobis(pyridine)platinum(II), is researched, Molecular C10H10Cl2N2Pt, CAS is 15227-42-6, about Unusual chemical behavior and molecular structure of a platinum(II) complex with N,N-diethylhydroxylamine. Author is Kuz’mina, L. G.; Porai-Koshits, M. A.; Vorob’ev-Desyatovskii, N. V..
cis-[PtL2Cl2] (L = Et2NOH) was prepared by the reaction of K2PtCl4 with L. cis-[PtL2Cl2] does not react with amines (NH3, pyridine, Et2NOH) and L does not react with cis-[PtA2Cl2] (A = NH3, py). cis-[PtL2Cl2] is monoclinic, space group C2, a 7.569(2), b 12.384(7), c 15.428(2) Å, β 100.00(2)°, Z = 4, R = 0.0287. One L coordinates to Pt through the N atom whereas the other is in the zwitterionic form and coordinates through the O atom. The low reactivity of cis-[PtL2Cl2] in substitution reactions is explained on the basis of H bonding and agostic interactions due to which the axial positions in the square planar complexes are blocked against nucleophilic attack.
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Reference:
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