Extracurricular laboratory: Synthetic route of 693-67-4

Here is just a brief introduction to this compound(693-67-4)Product Details of 693-67-4, more information about the compound(1-Bromoundecane) is in the article, you can click the link below.

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Iron(II) and Copper(I) Control the Total Regioselectivity in the Hydrobromination of Alkenes, published in 2021-08-06, which mentions a compound: 693-67-4, mainly applied to alkyl bromide preparation regioselective; alkene hydrobromination, Product Details of 693-67-4.

A new method that allowed the complete control of the regioselectivity of the hydrobromination reaction of alkenes was described. Herein, a radical procedure with TMSBr and oxygen as common reagents, where the formation of the anti-Markovnikov product occurs in the presence of ppm amounts of the Cu(I) species and the formation of the Markovnikov product occurred in the presence of 30 mol % iron(II) bromide was reported. D. functional theory calculations combined with Fukui’s radical susceptibilities support the obtained results.

Here is just a brief introduction to this compound(693-67-4)Product Details of 693-67-4, more information about the compound(1-Bromoundecane) is in the article, you can click the link below.

Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem