In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Rhodium-catalyzed direct alkylation of benzylic amines using alkyl bromides, published in 2019-01-31, which mentions a compound: 693-67-4, mainly applied to benzylmethylamino pyridine alkyl bromide rhodium catalyzed alkylation; Catalysis; C–H activation; C–H functionalization; Directing group, Electric Literature of C11H23Br.
The development and substrate scope evaluation of a direct alkylation protocol of the C(sp3)-H bond of benzylic amines using alkyl bromides was reported. This pyridine-directed method was initiated by elimination of the alkyl bromide to a terminal olefin, which was then the true alkylating agent.
Compound(693-67-4)Electric Literature of C11H23Br received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(1-Bromoundecane), if you are interested, you can check out my other related articles.
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem