The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 4-Amino-2-(tert-butyl)pyrimidine(SMILESS: NC1=NC(C(C)(C)C)=NC=C1,cas:114362-20-8) is researched.Formula: C6H6N2O. The article 《σ-Adduct formation between amines and liquid ammonia. Part 47. On the Chichibabin amination of pyrimidine and N-alkylpyrimidinium salts using liquid ammonia/potassium permanganate》 in relation to this compound, is published in Journal of Heterocyclic Chemistry. Let’s take a look at the latest research on this compound (cas:114362-20-8).
4-Aminopyrimidines I (R1 = C1-4 alkyl) and iminodihydropyrimidines II (R2 = Et, CHMe2) were prepared 2-Alkylpyrimidines were treated with KNH2-NH3-KMnO4 to give I. The reaction of 1,2-diethylpyrimidinium fluoroborate with NH3-KMnO4 gave II (R2 = Et).
From this literature《σ-Adduct formation between amines and liquid ammonia. Part 47. On the Chichibabin amination of pyrimidine and N-alkylpyrimidinium salts using liquid ammonia/potassium permanganate》,we know some information about this compound(114362-20-8)Quality Control of 4-Amino-2-(tert-butyl)pyrimidine, but this is not all information, there are many literatures related to this compound(114362-20-8).
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem