Electric Literature of C10H10Cl2N2Pt. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: cis-Dichlorobis(pyridine)platinum(II), is researched, Molecular C10H10Cl2N2Pt, CAS is 15227-42-6, about Platinum(II) complexes in the catalytic hydrosilylation of acetophenone. Kinetics of the reaction and the effect of ligands. Author is Lasitsa, N. A.; Skvortsov, N. K.; Lobadyuk, V. I.; Spevak, V. N.; Esina, G. A.; Abramova, I. P.; Lazarev, S. Ya..
A kinetic study of hydrosilylation of MeCOPh with MeSiHCl2 or MeSiPhH2 in the presence of LL1PtX2 (X = Cl, Br; L = L1 = Me2SO, Et2SO, py, Et3P, MeSOC6H4Me-4; L = C2H4, L1 = Me2SO, Et2SO; L = py, L1 = Et2SO; L = MeSOC6H4Me-4, L1 = Bu3P) catalysts showed a relationship between the ligand type and catalytic activity. In contrast with bis(phosphine) and bis(olefin) complexes, bis(sulfoxide) complexes and all complexes with mixed ligands, one of which is sulfoxide, show high catalytic activity. For the reaction with MeSiHCl2, the order of reactivity is olefin > SO > P(III) > py, close to an analogous relationship for the hydrosilylation of olefins.
In addition to the literature in the link below, there is a lot of literature about this compound(cis-Dichlorobis(pyridine)platinum(II))Electric Literature of C10H10Cl2N2Pt, illustrating the importance and wide applicability of this compound(15227-42-6).
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem