Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 1-Bromoundecane, is researched, Molecular C11H23Br, CAS is 693-67-4, about Cobalt-Catalyzed Decarboxylative Methylation and Ethylation of Aliphatic N-(Acyloxy)phthalimides with Organoaluminum Reagents.Related Products of 693-67-4.
A cobalt-catalyzed decarboxylative methylation of aliphatic redox-active esters [N-(acyloxy)phthalimides; RAEs] I (R = heptadecyl, 1-[(4-methylphenyl)sulfonyl]piperidin-4-yl, 1-benzoylpyrrolidin-2-yl, 4-(4-chlorophenoxy)butyl, etc.) with trimethylaluminum under mild conditions was developed, providing a method for transforming a carboxylate group into a Me group without redox fluctuation. Primary and secondary RAEs I were both amenable substrates, whereas a tertiary RAE delivered an elimination product. Triethylaluminum was also used to deliver a decarboxylative ethylation product RC2H5.
As far as I know, this compound(693-67-4)Related Products of 693-67-4 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem