Recommanded Product: 1-Bromoundecane. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 1-Bromoundecane, is researched, Molecular C11H23Br, CAS is 693-67-4, about Cobalt-Catalyzed Decarboxylative Methylation and Ethylation of Aliphatic N-(Acyloxy)phthalimides with Organoaluminum Reagents. Author is Wang, Ze-Zhong; Wang, Guang-Zu; Zhao, Bin; Shang, Rui; Fu, Yao.
A cobalt-catalyzed decarboxylative methylation of aliphatic redox-active esters [N-(acyloxy)phthalimides; RAEs] I (R = heptadecyl, 1-[(4-methylphenyl)sulfonyl]piperidin-4-yl, 1-benzoylpyrrolidin-2-yl, 4-(4-chlorophenoxy)butyl, etc.) with trimethylaluminum under mild conditions was developed, providing a method for transforming a carboxylate group into a Me group without redox fluctuation. Primary and secondary RAEs I were both amenable substrates, whereas a tertiary RAE delivered an elimination product. Triethylaluminum was also used to deliver a decarboxylative ethylation product RC2H5.
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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem