So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Peloso, Arnaldo researched the compound: cis-Dichlorobis(pyridine)platinum(II)( cas:15227-42-6 ).Reference of cis-Dichlorobis(pyridine)platinum(II).They published the article 《Kinetics of oxidation of dichlorobis(substituted pyridine)platinum(II) and of reduction of tetrachlorobis(substituted pyridine)platinum(IV) complexes》 about this compound( cas:15227-42-6 ) in Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999). Keywords: chloropyridineplatinum complex oxidation reduction kinetics; pyridinechloroplatinum complex oxidation reduction kinetics; platinum pyridine complex oxidation reduction. We’ll tell you more about this compound (cas:15227-42-6).
The kinetics of oxidation of cis-[PtCl2L2] (L = py, 3-methyl-, 3- and 4-chloro-, 3- and 4-cyanopyridine) by [AuCl4]- in the presence of [NEt4]Cl and of reduction of cis-[PtCl4L2] by [NEt4]I were studied in MeCN. The rate law for the oxidation reaction was rate = k3[PtCl2L2][AuCl4-][Cl-], where k3 was unaffected by changes in L and had a value ∼100 times higher than that previously found for related phenanthrolineplatinum(II) complexes. The rate law for the reduction reaction was rate = k2[PtCl4L2][I-], where k2 was influenced by the basicity of L, as in related phenanthrolineplatinum(IV) complexes. The kinetic results were discussed in terms of σ and π interactions between the Pt and L.
Although many compounds look similar to this compound(15227-42-6)Reference of cis-Dichlorobis(pyridine)platinum(II), numerous studies have shown that this compound(SMILES:[Cl-][Pt+2]([N]1=CC=CC=C1)([Cl-])[N]2=CC=CC=C2), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem