Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 15227-42-6, is researched, Molecular C10H10Cl2N2Pt, about Kinetics of oxidation of dichlorobis(substituted pyridine)platinum(II) and of reduction of tetrachlorobis(substituted pyridine)platinum(IV) complexes, the main research direction is chloropyridineplatinum complex oxidation reduction kinetics; pyridinechloroplatinum complex oxidation reduction kinetics; platinum pyridine complex oxidation reduction.Safety of cis-Dichlorobis(pyridine)platinum(II).
The kinetics of oxidation of cis-[PtCl2L2] (L = py, 3-methyl-, 3- and 4-chloro-, 3- and 4-cyanopyridine) by [AuCl4]- in the presence of [NEt4]Cl and of reduction of cis-[PtCl4L2] by [NEt4]I were studied in MeCN. The rate law for the oxidation reaction was rate = k3[PtCl2L2][AuCl4-][Cl-], where k3 was unaffected by changes in L and had a value ∼100 times higher than that previously found for related phenanthrolineplatinum(II) complexes. The rate law for the reduction reaction was rate = k2[PtCl4L2][I-], where k2 was influenced by the basicity of L, as in related phenanthrolineplatinum(IV) complexes. The kinetic results were discussed in terms of σ and π interactions between the Pt and L.
The article 《Kinetics of oxidation of dichlorobis(substituted pyridine)platinum(II) and of reduction of tetrachlorobis(substituted pyridine)platinum(IV) complexes》 also mentions many details about this compound(15227-42-6)Safety of cis-Dichlorobis(pyridine)platinum(II), you can pay attention to it, because details determine success or failure
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem