More research is needed about 118864-75-8

118864-75-8, Name is (S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline, belongs to tetrahydroisoquinoline compound, is a common compound. Recommanded Product: (S)-1-Phenyl-1,2,3,4-tetrahydroisoquinolineIn an article, once mentioned the new application about 118864-75-8.

3-Hydroxypyrroles and 1H-Pyrrol-3(2H)-ones. Part 3. Pyrrolones from Pyrolyses of Aminomethylene Meldrum’s Acid Derivatives: Loss of Chirality at the Site of Hydrogen Transfer.

Pyrolysis of the diastereoisomeric Meldrum’s acid derivatives (4) and (5), or of the chiral derivatives (6), (7), and (9), gives 2,2-disubstituted 1H-pyrrol-3(2H)-ones in which there is loss of configuration at the reaction site .The extent of configuration loss is greater if the reaction site is part of a ring.These results are explained by a two-step, hydrogen-transfer-cyclisation mechanism, following initial generation of a methyleneketene.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem