In heterogeneous catalysis, the catalyst is in a different phase from the reactants. SDS of cas: 57196-62-0, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 57196-62-0, name is 6-Methoxy-1,2,3,4-tetrahydroisoquinoline hydrochloride. In an article£¬Which mentioned a new discovery about 57196-62-0
Iodine release and recovery, influence of polyiodide anions on electrical conductivity and nonlinear optical activity in an interdigitated and interpenetrated bipillared-bilayer metal-organic framework
{[Cu6(pybz)8(OH)2]¡¤I 5-¡¤I7-}n (1), obtained hydrothermally by using iodine molecules as a versatile precursor template, consists of a cationic framework with two types of zigzag channels, which segregate I5- and I7- anions. The framework exhibits the first observed bipillared-bilayer structure featuring both interdigitation and interpenetration. 1 displays high framework stability in both acidic (HCl) and alkaline (NaOH) solutions. 1 slowly releases iodine in dry methanol to give [Cu6(pybz)8(OH)2](I -)2¡¤3.5CH3OH (1′) and partially recovers iodine from cyclohexane to form [Cu6(pybz)8(OH) 2](I-)2¡¤xI2 (1?). Differences of up to 100 times in electrical conductivity and of 4 times in nonlinear optical activity (NLO) have been measured between 1 and 1′. This compound is one of few displaying multifunctionality, electrical conductivity, NLO, and crystal-crystal stability upon release and recovery of iodine. It is also unique in the iodine release from polyiodide anions in a metal-organic framework.
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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem