Research speed reading in 2021. Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent，Which mentioned a new discovery about SDS of cas: 3340-78-1, molcular formula is C15H15N, introducing its new discovery. , SDS of cas: 3340-78-1
Thiourea-based hydrogen bond donor has been recently disclosed by our group to be an efficient organocatalyst for cross-dehydrogenative coupling (CDC) reactions. Here we present a detailed mechanistic study of this reaction using NMR spectroscopy and kinetic isotope effect experiment. The results revealed that alpha-amino peroxide is the true intermediate within the catalytic cycle, formed via a thiourea-catalyzed rate-determining hydrogen atom transfer (HAT) process. These experimental investigations not only provide somewhat insight into the mechanism of thiourea-catalyzed CDC reactions but also promote their further applications.
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Referenceï¼?br>Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem