The effect of the change of synthetic route on the product 15227-42-6

From this literature《Effect of catalyst structure on the reaction of α-methylstyrene with 1,1,3,3-tetramethyldisiloxane》,we know some information about this compound(15227-42-6)Recommanded Product: cis-Dichlorobis(pyridine)platinum(II), but this is not all information, there are many literatures related to this compound(15227-42-6).

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Russian Journal of General Chemistry called Effect of catalyst structure on the reaction of α-methylstyrene with 1,1,3,3-tetramethyldisiloxane, Author is Vekki, D. A.; Skvortsov, N. K., which mentions a compound: 15227-42-6, SMILESS is [Cl-][Pt+2]([N]1=CC=CC=C1)([Cl-])[N]2=CC=CC=C2, Molecular C10H10Cl2N2Pt, Recommanded Product: cis-Dichlorobis(pyridine)platinum(II).

Reaction of α-methylstyrene with 1,1,3,3-tetramethyldisiloxane in the presence of the complexes of Pt(II), Pd(II) and Rh(I) is explored. In the presence of Pt catalyst, hydrosilylation of α-methylstyrene occurs predominantly giving β-adduct, while on Pd catalysts proceeds reduction of α-methylstyrene and on Rh catalysts both processes take place. In the reaction mixture proceeds disproportion and dehydro-condensation of 1,1,3,3-tetramethyldisiloxane that gives long chain linear and cyclic siloxanes HMe2Si(OSiMe2)nH and (-OSiMe2-)m (n = 2-6, m = 3-7), resp. Platinum catalysts promotes formation of linear siloxanes, while both Rh and Pd catalysts afford linear and cyclic siloxanes as well. Structure of intermediate metallo-complexes was studied.

From this literature《Effect of catalyst structure on the reaction of α-methylstyrene with 1,1,3,3-tetramethyldisiloxane》,we know some information about this compound(15227-42-6)Recommanded Product: cis-Dichlorobis(pyridine)platinum(II), but this is not all information, there are many literatures related to this compound(15227-42-6).

Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem