Product Details of 15227-42-6. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: cis-Dichlorobis(pyridine)platinum(II), is researched, Molecular C10H10Cl2N2Pt, CAS is 15227-42-6, about Stereospecific synthesis of cyclobutanol derivatives using a 5 minus 1 methodology and platinum(II). Author is Stewart, Frederick F.; Jennings, P. W..
Cycloaddition reaction of the carbene N2CHCO2Et to norbornene in the presence of Rh(II) gave 95% tricyclic esters I (R = CO2Et), which were reduced with LiAlH4 to give 63% I (R = CH2OH) (II). Kinetic resolution of II by oxidative insertion with Pt(py)2Cl2 gave 93% complex III (R = CH2OH) and its isomer, which underwent stereospecific acid-catalyzed ring expansion to give 70-80% complexes IV (R1 = H, Me, CHO; L = py) and their isomers. Ligand substitution with P(OMe)3 gave 100% IV [L = P(OMe)3], which underwent reductive elimination on heating to give 80-90% III (R = OR1).
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