Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: cis-Dichlorobis(pyridine)platinum(II), is researched, Molecular C10H10Cl2N2Pt, CAS is 15227-42-6, about Palladium(II) and platinum(II) saccharinate complexes containing pyridine and 3-acetylpyridine: Synthesis, crystal structures, fluorescence and thermal properties.Related Products of 15227-42-6.
New Pd(II) and Pt(II) complexes of saccharinate (sac), trans-[Pd(py)2(sac)2] (1), cis-[Pt(py)2(sac)2] (2), trans-[Pd(3-acpy)2(sac)2] (3) and cis-[Pt(3-acpy)2(sac)2] (4) (py = pyridine and 3-acpy = 3-acetylpyridine) were synthesized. Elemental anal., UV-visible, IR, NMR and TG/DTA characterizations were carried out. The structures of 1-4 were determined by x-ray diffraction. The Pd(II) and Pt(II) ions are coordinated by two N-bonded sac ligands, and two N atoms of py or 3-acpy, forming a distorted square-planar geometry. The Pd(II) complexes (1 and 3) are trans isomers, while the Pt(II) complexes (2 and 4) are cis isomers. The mononuclear species in the solid state are connected by weak intermol. C-H···O H bonds, C-H···π and π···π stacking interactions. The Pt(II) complexes show significant fluorescence at room temperature
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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem