The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: cis-Dichlorobis(pyridine)platinum(II)( cas:15227-42-6 ) is researched.Application of 15227-42-6.Stetsenko, A. I.; Dmitrieva, E. S.; Yakovlev, K. I. published the article 《The investigation of platinum(II) complexes with adenine, adenosine and 2-aminopyrimidines》 about this compound( cas:15227-42-6 ) in Journal of Clinical Hematology and Oncology. Keywords: platinum adenine adenosine aminopyrimidine; adenine platinum complex; adenosine platinum complex; aminopyrimidine platinum complex; pyrimidine amino platinum complex; ammine platinum complex; pyridine platinum complex; ethylenediamine platinum complex. Let’s learn more about this compound (cas:15227-42-6).
[Pt2(NH3)4Cl2L]Cl2 (L = adenine, adenosine) were prepared by the addition of ligand to cis-[Pt(NH3)2Cl2] solution [Pt(NH3)2L](NO3)2 were obtained by adding L to cis-[Pt(NH3)2(H2O)2](NO3)2 solution 2-Aminopyrimidine (L1) and 2-amino-4-phenylpyrimidine (L2) reacted with aqueous K2[PtCl4] to yield trans-[PtL12Cl2] and trans-[PtL22Cl2], resp. The cis-[PtA2L12]Cl2 (A = NH3, pyridine, 0.5 ethylenediamine) were obtained by the substitution reaction of cis-[PtA2Cl2] with 2-aminopyrimidine. The cis-[PtA2(H2O)2](NO3)2 reacted with 2-aminopyrimidine to afford cis-[PtA2L12](NO3)2 and cis-[PtA2L1](NO3)2 (A = NH3, 0.5 ethylenediamine), depending on the stoichiometric ratios of the reactants.
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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem