The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 1-Bromoundecane( cas:693-67-4 ) is researched.Application of 693-67-4.Anschuber, Martin; Pollice, Robert; Schnuerch, Michael published the article 《Rhodium-catalyzed direct alkylation of benzylic amines using alkyl bromides》 about this compound( cas:693-67-4 ) in Monatshefte fuer Chemie. Keywords: benzylmethylamino pyridine alkyl bromide rhodium catalyzed alkylation; Catalysis; C–H activation; C–H functionalization; Directing group. Let’s learn more about this compound (cas:693-67-4).
The development and substrate scope evaluation of a direct alkylation protocol of the C(sp3)-H bond of benzylic amines using alkyl bromides was reported. This pyridine-directed method was initiated by elimination of the alkyl bromide to a terminal olefin, which was then the true alkylating agent.
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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem