Kong, Pi-Chang; Rochon, F. D. published the article 《Reactions of potassium tetrachloroplatinate(II) with pyridine derivatives in dimethylformamide and synthesis of potassium trichloro(pyridine)platinum(II)》. Keywords: platinum pyridine derivative complex; picoline platinum complex; lutidine platinum complex.They researched the compound: cis-Dichlorobis(pyridine)platinum(II)( cas:15227-42-6 ).Name: cis-Dichlorobis(pyridine)platinum(II). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:15227-42-6) here.
The reactions of K2PtCl4 with pyridine derivatives L (L = py = pyridine, pic = picoline, and lut = lutidine) were studied in DMF. K[PtLCl3] (I) were isolated and the yield decreased with the order, 2,4-lut = 2-pic > 2,6-lut > 4-pic = py, which can be correlated to the steric hindrance of the ortho Me groups. Cis-[PtL2Cl2] (II) is the final product of the reactions. Trans-[PtL2Cl2] (III) can also be obtained from a DMF solution of [Pt(L)4]Cl2 (L = py) at room temperature A comparison of the above reactions in H2O and in DMF was also made.
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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem