So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Wang, Ze-Zhong; Wang, Guang-Zu; Zhao, Bin; Shang, Rui; Fu, Yao researched the compound: 1-Bromoundecane( cas:693-67-4 ).Quality Control of 1-Bromoundecane.They published the article 《Cobalt-Catalyzed Decarboxylative Methylation and Ethylation of Aliphatic N-(Acyloxy)phthalimides with Organoaluminum Reagents》 about this compound( cas:693-67-4 ) in Synlett. Keywords: acyloxyphthalimide organoaluminum reagent decarboxylative methylation ethylation cobalt catalyst. We’ll tell you more about this compound (cas:693-67-4).
A cobalt-catalyzed decarboxylative methylation of aliphatic redox-active esters [N-(acyloxy)phthalimides; RAEs] I (R = heptadecyl, 1-[(4-methylphenyl)sulfonyl]piperidin-4-yl, 1-benzoylpyrrolidin-2-yl, 4-(4-chlorophenoxy)butyl, etc.) with trimethylaluminum under mild conditions was developed, providing a method for transforming a carboxylate group into a Me group without redox fluctuation. Primary and secondary RAEs I were both amenable substrates, whereas a tertiary RAE delivered an elimination product. Triethylaluminum was also used to deliver a decarboxylative ethylation product RC2H5.
Although many compounds look similar to this compound(693-67-4)Quality Control of 1-Bromoundecane, numerous studies have shown that this compound(SMILES:CCCCCCCCCCCBr), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem