Name: cis-Dichlorobis(pyridine)platinum(II). The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: cis-Dichlorobis(pyridine)platinum(II), is researched, Molecular C10H10Cl2N2Pt, CAS is 15227-42-6, about Research at ICI Central Petrochemical and Polymer Laboratory, Runcorn Heath. NQR spectrometry. Author is Fryer, C. W..
The use of 35Cl nuclear quadrupole resonance (NQR) in the study of transition metal compounds is discussed. In the NQR spectra of cis-and trans-L2PtCl2, the difference in the 35Cl NQR frequencies (νtrans-νcis) increases 0.95, 1.98, 3.1 MHz, for L = Me2NH, pyridine, and Bu3P, resp. Frequency variation is greater among the trans compounds Charge donating properties of L to Pt have a larger effect on the ν 35 Cl attached to the Pt than does the weakening influence of L. The 35Clν for bridging Cl in trans-L2Pt2Cl4 and trans-L2Pd2Cl4 are much lower (at 15.46 and 12.84 MHz, resp.) than the frequencies of the terminal Cl(at 22.36 and 19.56 MHz). This difference can be used in studying cluster compounds
After consulting a lot of data, we found that this compound(15227-42-6)Name: cis-Dichlorobis(pyridine)platinum(II) can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
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