Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1452-77-3, is researched, SMILESS is O=C(N)C1=NC=CC=C1, Molecular C6H6N2OJournal, Asian Journal of Organic Chemistry called Picolinamide-Based Iridium Catalysts for Aqueous Formic Acid Dehydrogenation: Increase in Electron Density of Amide N through Substituents, Author is Guo, Jian; Yin, Chengkai; Li, Maoliang; Zhong, Dulin; Zhang, Yuguan; Li, Xiaobin; Wang, Yilin; Yao, Hong; Qi, Tiangui, the main research direction is formic acid picolinamide iridium catalyst dehydrogenation.Application In Synthesis of Picolinamide.
Formic acid (FA) is considered to be a potential hydrogen storage material. Homogeneous catalysts are desired, which decompose aqueous FA into H2 and CO2 without addition of organic additives as they can contaminate the generated gas mixture We report a new series of Cp*Ir (Cp*=pentamethylcyclopentadienyl) catalysts featuring picolinamide-based ligands for efficient H2 generation from FA solution Among them in-situ generated catalyst from [Cp*Ir(H2O)3]SO4 and picolinohydroxamic acid (L3) achieved a high turnover frequency (TOF) of 90625 h-1 at 80 °C in 0.9 M FA solution and a turnover number (TON) of 120520 at 80 °C in a recycle experiment The substituent effect of amide N atom was discussed and a plausible mechanism was proposed based on the exptl. results.
After consulting a lot of data, we found that this compound(1452-77-3)Application In Synthesis of Picolinamide can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem