Category: 1452-77-3

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Separation and Purification Technology called Dipicolinamide functionalized titania for highly efficient sorption of tetra and hexavalent actinide, Author is Pahan, Sumit; Sengupta, Arijit; Musharaf Ali, Sk.; Debnath, A. K.; Banerjee, D.; Vincent, T.; Sugilal, G.; Kaushik, C. P., which mentions a compound: 1452-77-3, SMILESS is O=C(N)C1=NC=CC=C1, Molecular C6H6N2O, Synthetic Route of C6H6N2O.

Dipicolinamide functionalized titania particles have been synthesized for efficient decontamination of uranyl and thorium ions from aqueous acidic waste solution Langmuir isotherm was found to be predominating with maximum sorption capacity of 125 mg/g for Th and 111 mg/g for U, resp. The sorption was found to follow pseudo 2nd order kinetics predominately, with rate constant 8.6E-04 mg g-1 min-1 for Th and 6.1E-04 mg g-1 min-1 for U, resp. Up to 200 kGy of gamma irradiation, not much deterioration in extraction performance of sorbent material was observed Three contacts of 0.1 M aqueous solutions of oxalic acid and sodium carbonate were found to be effective in quant. elution of Th4+ and UO2+2 from the loaded sorbent, resp. The sorption of U and Th on dipicolinamide functionalized titania was evidenced by SEM images, elemental mapping and the EDX. Theor. investigation revealed that, the solution phase free energy of sorption (ΔGsol) was higher for Th4+ (-114.1 kcal mol-1) compared to UO2+2 (-80.41 kcal mol-1).

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Picolinamide, is researched, Molecular C6H6N2O, CAS is 1452-77-3, about Half-Sandwich Iridium Complexes for the One-Pot Synthesis of Amides: Preparation, Structure, and Diverse Catalytic Activity, the main research direction is iridium half sandwich Schiff base complex preparation hydration catalyst; nitrile hydration oxime rearrangement preparation aromatic amide iridium catalyst; crystal structure iridium half sandwich Schiff base complex; mol structure iridium half sandwich Schiff base complex.Category: tetrahydroisoquinoline.

Several types of air-stable N,O-coordinate half-sandwich iridium complexes containing Schiff base ligands with the general formula [Cp*IrClL] were synthesized in good yields. These stable iridium complexes displayed a good catalytic efficiency in amide synthesis. A variety of amides with different substituents were obtained in a one-pot procedure with excellent yields and high selectivities through the amidation of aldehydes with NH2OH·HCl and nitrile hydration under the catalysis of complexes 1-4. The excellent and diverse catalytic activity, mild conditions, broad substance scope, and environmentally friendly solvent make this system potentially applicable in industrial production Half-sandwich iridium complexes 1-4 were characterized by NMR, elemental anal., and IR techniques. Mol. structures of complexes 2 and 3 were confirmed by single-crystal X-ray anal. Half-sandwich iridium complexes were synthesized, which exhibited a high catalytic activity for amide synthesis in a one-pot procedure with excellent yields and high selectivity through aldehyde amidation or nitrile hydration. The broad substrate scope, mild reaction conditions, and high yields of the products made this catalytic system attractive in the industrial process.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 1452-77-3, is researched, Molecular C6H6N2O, about Magnetically enhanced polymersupported ceria nanocatalysts for the hydration of nitriles, the main research direction is magnetite nitrile polystyrene ceria nanocatalyst hydration heterogeneous catalysis.Electric Literature of C6H6N2O.

The heterogeneous catalysis of the hydration of nitriles to amides is a process of great industrial relevance in which cerium(IV) oxide (also referred to as ceria) has shown an outstanding catalytic performance. The use of non-supported ceria nanoparticles is related to difficulties in the purification of the product and the recovery and recyclability of the catalyst. Therefore, in this work, ceria nanoparticles are supported on a polymer matrix either by synthesizing polymer particles by so-called Pickering miniemulsions while using ceria nanoparticles as emulsion stabilizers or, as a comparison, by in-situ crystallization on preformed polymer particles. The former strategy presents significant advantages over the latter in terms of time and consumption of resources, and it facilitates an easier scale-up of the process. In both strategies, the incorporation of a magnetoresponsive core within the polymer matrix allows the recovery and the recycling of the catalyst by simple application of a magnetic field and offers an enhancement of the catalytic efficiency.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

Recommanded Product: Picolinamide. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Picolinamide, is researched, Molecular C6H6N2O, CAS is 1452-77-3, about Aerobic Activation of C-H Bond in Amines Over a Nanorod Manganese Oxide Catalyst. Author is Wang, Hai; Wang, Liang; Wang, Sai; Dong, Xue; Zhang, Jian; Xiao, Feng-Shou.

The development of heterogeneous catalysts for the synthesis of pharmaceutically relevant compounds is always important for chem. research. Here, we report a selective aerobic oxidation of aromatic and aliphatic amines to corresponding amides over a nanorod manganese oxide (NR-MnOx) catalyst. The kinetic studies reveal that the NR-MnOx catalyzed amine-to-amide reaction proceeds the oxidative dehydrogenation of the amines into nitriles, followed by hydrolysis of nitrile into amides. The NR-MnOx exhibits fast kinetics and high selectivities in these steps, as well as hinders the byproduct formation. More importantly, the NR-MnOx catalyst is stable and reusable in the continuous recycle tests with water as a sole byproduct, exhibiting superior sustainability and significant advancement to outperform the traditional amide production route in acidic or basic media with toxic byproducts.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

Product Details of 1452-77-3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Picolinamide, is researched, Molecular C6H6N2O, CAS is 1452-77-3, about Characterization of copper(II) specific pyridine containing ligands: Potential metallophores for Alzheimer’s disease therapy.

Two amide group containing pyridine derivatives, N-(pyridin-2-ylmethyl)picolinamide (PMPA) and N-(pyridin-2-ylmethyl)-2-((pyridin-2-ylmethyl)amino)acetamide (DPMGA), have been investigated as potential metallo-phores in the therapy of Alzheimer’s disease. Their complex formation with Cu(II) and Zn(II) were characterized in details. Unexpectedly not only the Cu(II) but also the Zn(II) was able to induce deprotonation of the amide-NH, however, it occurred only at higher pH or at higher metal ion concentrations than the biol. conditions. At μM concentration level mono complexes (MLH-1) dominate with both ligands. Direct fluorescence and reactive oxygen species (ROS) producing measurements prove that both ligands are able to remove Cu(II) from its amyloid-β complexes (CuAβ). Correlation was also established between the conditional stability constant of the Cu(II) complexes with different ligands and their ability of inhibition of ROS production by CuAβ.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Picolinamide( cas:1452-77-3 ) is researched.Recommanded Product: Picolinamide.Das, Debasish; Hashmi, Sabiha; Sengupta, Arijit; Kannan, S.; Kaushik, C. P. published the article 《Understanding the extraction behaviour of UO2+2 and Th4+ using novel picolinamide/N-oxo picolinamide in ionic liquid: A comparative evaluation with molecular diluent》 about this compound( cas:1452-77-3 ) in Journal of Molecular Liquids. Keywords: uranium oxide ligand diluent viscosity cation exchange thermodn extraction. Let’s learn more about this compound (cas:1452-77-3).

The manuscript deals with efficient separation of hexavalent UO2+2 and tetravalent Th4+ from aqueous acidic waste solution in green way using ionic liquid with novel picolinamide (L I) and N-oxo picolinamide (L II) based ligands. A comparative evaluation was carried out to understand the extraction mechanism, kinetics, thermodn., speciation, radiolytic stability and stripping behavior of UO2+2 and Th4+ in ionic liquid vis-a-vis mol. diluent. The investigation demonstrates the predominance of cation exchange mechanism in ionic liquid and solvation mechanism in n-dodecane based systems. The slower extraction kinetics in ionic liquid was attributed to the viscosity effect. The extractive mass transfer processes were found to be spontaneous, endothermic and entropically driven in nature. The picolinamide and N-oxo picolinamide ligands were found to form inner-sphere complexes in ionic liquid as well as n-dodecane. The CO2-3 was more effective aqueous phase complexing agent to back extract UO2+2, while C2O2-4 exhibited the same for Th4+.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

Product Details of 1452-77-3. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Picolinamide, is researched, Molecular C6H6N2O, CAS is 1452-77-3, about New insights into the function of the proteins IsiC and IsiD from Synechocystis sp. PCC 6803 under iron limitation. Author is Cheng, Yarui; Zhang, Tianyuan; Cao, Yangrong; Wang, Li; Chen, Wenli.

Iron is a common cofactor in biol. processes such as respiration, photosynthesis, and nitrogen fixation. The genes isiC and isiD encode unknown proteins, and the growth of ΔisiC and ΔisiD mutants is inhibited under iron-deficient conditions. To study the regulatory mechanisms of IsiC and IsiD during iron starvation, we carried out transcriptome and metabolome sequencing. The Kyoto Encyclopedia of Genes and Genomes (KEGG) anal. showed that the photosynthesis, nitrogen metabolism, and ABC transporter pathways play a vital role in regulating iron deficiency. Upon iron repletion, IsiC and IsiD also have a regulatory effect on these pathways. Addnl., KEGG anal. of the differential metabolites of wild type (WT) and mutants showed that they were all enriched in starch and sucrose metabolism after iron limitation. Weighted gene co-expression network anal. (WGCNA) constructed a co-expression network of differentially expressed genes with phenotypes and metabolites, and finally identified five modules. The turquoise module was pos. correlated with iron deficiency. In contrast, the WT and blue module exhibited a neg. correlation, and the mutants ΔisiC and ΔisiD were pos. correlated with the gray and brown modules, resp. WGCNA also analyzed the relationship between metabolites and phenotypes, and the green module was related to iron starvation. The co-expression network determined the hub genes and metabolites of each module. This study lays a foundation for a better understanding of cyanobacteria in response to iron deficiency.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Picolinamide( cas:1452-77-3 ) is researched.Related Products of 1452-77-3.Gupta, Nikitra N.; Punekar, Amrin S.; Raj, Karthik Raja E. K.; Ghodekar, Medha M.; Patil, Vipul S.; Gopinath, Chinnakonda S.; Raja, Thirumalaiswamy published the article 《Phase Transfer Ceria-Supported Nanocatalyst for Nitrile Hydration Reaction》 about this compound( cas:1452-77-3 ) in ACS Omega. Keywords: ceria supported rare earth metal oxide preparation characterization; nitrile hydration reaction phase transfer catalyst. Let’s learn more about this compound (cas:1452-77-3).

The present study elaborates the catalytic effect of rare-earth metal oxides (Sm2O3 and La2O3) over ceria as a support phase transfer catalyst. The synthesized catalysts have been subjected to different characterization techniques, such as field-emission SEM, high-resolution transmission electron microscopy, powder X-ray diffraction, N2 adsorption-desorption (BET surface anal.), temperature-programmed desorption study (NH3/CO2-TPD), Fourier transform IR, Raman anal., and XPS to get better insights into the catalytic activity of the catalysts for hydration of nitrile.

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Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Picolinamide, is researched, Molecular C6H6N2O, CAS is 1452-77-3, about Hydration of nitriles using a metal-ligand cooperative ruthenium pincer catalyst, the main research direction is nitrile water ruthenium pincer catalyst hydration; amide preparation.Category: tetrahydroisoquinoline.

The catalytic nitrile hydration using ruthenium catalysts based on a pincer scaffold with a dearomatized pyridine backbone. These complexes catalyzed the nucleophilic addition of H2O to a wide variety of aliphatic and (hetero)aromatic nitriles in tBuOH as solvent. Reactions occurred under mild conditions (room temperature) in the absence of additives. A mechanism for nitrile hydration was proposed that is initiated by metal-ligand cooperative binding of the nitrile.

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Tetrahydroisoquinoline – Wikipedia,
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