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New Advances in Chemical Research, May 2021. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. Related Products of 3340-78-1, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 3340-78-1, name is 2-Phenyl-1,2,3,4-tetrahydroisoquinoline. In an article,Which mentioned a new discovery about 3340-78-1

Metal-based surface active ionic liquids (MSAILs), 1-alkyl-3-methyl imidazoliumtetrachloromanganate [Cnmim][MnCl4]2 ? (n= 8,10,12) have been synthesized and characterized for self-assembling behavior in aqueous solution using tensiometry, fluorescence, conductivity, dynamic light scattering (DLS) and transmission electron microscopy (TEM) techniques. MSAILs have exhibited 4 to 5 fold higher surface activity as compared to the non-metal based surface active ionic liquids. MSAILs micellar solutions have been successfully used for C(sp3)-H functionalized oxidative cyanation of the tertiary amines. Oxidative Strecker reaction was carried out with different concentrations of the MSAILs, cyanide source (TMSCN) and substrate, and moderate to very high yields (up to 95%) could be achieved in 3?4 h. Usually, cyanation of tertiary amines is carried out in organic solvents under harsh conditions without recycling of the catalyst. Herein aqueous MSAILs micellar solutions have been used as a solvent, catalyst as well as template with a good recycling ability, thus making the approach simpler, greener, and sustainable.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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We disclose a novel, heterogeneous catalytic approach for selective coupling of C1 of N-aryltetrahydroisoquinolines with C3 of indoles in the presence of mesoporous manganese oxides. Our work involves a detailed mechanistic investigation of the reaction on the catalyst surface, backed by DFT computational studies, to understand the superior catalytic activity of manganese oxides.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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The invention discloses an activating compound containing C – H bond in C – H of the key of the method, the method comprises: inert gas protection and visible light irradiation, containing the photocatalyst and solvent in the system, adding containing C – H compound of the key, the photocatalyst is a quantum dot. The invention also discloses a key compound containing C – H of the C – H bond functionalized method, the method comprises: inert gas protection and visible light irradiation, containing the photocatalyst and solvent in the system, adding containing C – H compound of the key, the photocatalyst for the quantum dot, and containing C – H to the compound of the key in the key functionalized C – H. The invention under protection of inert gas, by using visible light irradiation, realizing C – H key activation and alkene third functionalization of the C – H bond. The invention quantum dot as a photocatalyst, mild reaction conditions, without the participation of the oxidizing agent, the atom economy, catalyst can be reused. (by machine translation)

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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A convenient N-arylation of tetrahydroquinoline and tetrahydroisoquinoline is described using electron-poor, electron-neutral, or electron-rich arylhalide derivatives and palladium(II)-BINAP as a catalyst.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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This review, with over 600 references, summarizes the recent applications of photoredox catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo- or organo-compounds capable of absorbing visible light, resulting in an excited state species. This excited state species can donate or accept an electron from other substrates to mediate redox reactions at ambient temperature with high atom efficiency. These catalysts have been successfully implemented for the discovery of novel organic reactions and synthesis of added-value chemicals with an excellent control of selectivity and stereo-regularity. More recently, such catalysts have been implemented by polymer chemists to post-modify polymers in high yields, as well as to effectively catalyze reversible deactivation radical polymerizations and living polymerizations. These catalysts create new approaches for advanced organic transformation and polymer synthesis. The objective of this review is to give an overview of this emerging field to organic and polymer chemists as well as materials scientists.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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New discoveries in chemical research and development in 2021. In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Related Products of 3340-78-1, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 3340-78-1, name is 2-Phenyl-1,2,3,4-tetrahydroisoquinoline. In an article,Which mentioned a new discovery about 3340-78-1

An effective approach to C1-difluoromethylated tetrahydroisoquinoline derivatives has been developed through C-H functionalization of tertiary amines by visible-light photoredox catalysis. This method uses stable, easily obtained alpha,alpha-difluorinated gem-diol as the CF2 source. The corresponding products were obtained in moderate to high yields at ambient temperature. the Partner Organisations 2014.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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A metal-free protocol of direct C(sp3)-H cyanation with cyanobenziodoxolones functioning as both cyanating reagents and oxidants was developed. Unactivated substrates, such as alkanes, ethers and tertiary amines, were thereby transformed to the corresponding nitriles in moderate to high yields. Mechanistic studies indicated that the cyanation proceeded with two potential pathways, which is highly dependent on the substrates: (1) a free radical case for alkanes and ethers and (2) an oxidative case for tertiary amines.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Organic dyes can be excellent catalysts for photoredox chemistry, offering low price, low toxicity, and an exceptional range of available materials. Their use has been limited because in comparison to their transition-metal catalysts the spectroscopic, kinetic, and electrochemical information available is far more limited. To remediate this situation, we have determined the necessary data for 14 readily available dyes with excellent potential as photoredox catalysts. We have also demonstrated the utility of these dyes through visible-light-mediated reductive dehalogenation and Aza-Henry reactions. We envision that this collection of data will lead to an increase in the use of cationic dyes in photoredox processes because users will find the necessary information readily available.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Shedding new light on the right combination of catalysts: A new dual catalytic system for efficient C-H functionalization was developed. The appropriate choice of two metal catalysts allows the oxidative alkynylation of tertiary amines under mild and sustainable reaction conditions.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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A photoactive difluoroborate-based conjugated organic polymer (B-COP) with A3B2-type donor?acceptor arrays in the polymer framework was synthesized by direct polycondensation and exhibited amorphous structure, high thermal and photophysical stability. The B-COP was shown to be a highly efficient heterogeneous photocatalyst for a wide range of photocatalytic transformations, including the oxidative coupling of primary amine and cross-dehydrogenative coupling reactions between tetrahydroisoquinolines and nucleophiles such as nitromethane, nitroethane, acetone and phenylethyl ketone.

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Reference:
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem