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Library of Cationic Organic Dyes for Visible-Light-Driven Photoredox Transformations

Organic dyes can be excellent catalysts for photoredox chemistry, offering low price, low toxicity, and an exceptional range of available materials. Their use has been limited because in comparison to their transition-metal catalysts the spectroscopic, kinetic, and electrochemical information available is far more limited. To remediate this situation, we have determined the necessary data for 14 readily available dyes with excellent potential as photoredox catalysts. We have also demonstrated the utility of these dyes through visible-light-mediated reductive dehalogenation and Aza-Henry reactions. We envision that this collection of data will lead to an increase in the use of cationic dyes in photoredox processes because users will find the necessary information readily available.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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A visible-light-activated rhodium complex in enantioselective conjugate addition of alpha-amino radicals with Michael acceptors

We report an efficient enantioselective conjugate addition of photogenerated alpha-amino radicals to Michael acceptors catalyzed by a newly prepared chiral-at-metal rhodium complex. This protocol shows that a single Rh(iii) complex can serve not only as a Lewis acid but also as a photoredox catalyst to control the stereoselectivity during the bond formation.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Functionally diverse nucleophilic trapping of iminium intermediates generated utilizing visible light

Our previous studies into visible-light-mediated aza-Henry reactions demonstrated that molecular oxygen played a vital role in catalyst turnover as well as the production of base to facilitate the nucleophilic addition of nitroalkanes. Herein, improved conditions for the generation of iminium ions from tetrahydroisoquinolines that allow for versatile nucleophilic trapping are reported. The new conditions provide access to a diverse range of functionality under mild, anaerobic reaction conditions as well as mechanistic insights into the photoredox cycle.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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3340-78-1, Name is 2-Phenyl-1,2,3,4-tetrahydroisoquinoline, belongs to tetrahydroisoquinoline compound, is a common compound. COA of Formula: C15H15NIn an article, once mentioned the new application about 3340-78-1.

Tricarbonyl rhenium(i) tetrazolato and N-heterocyclic carbene complexes: Versatile visible-light-mediated photoredox catalysts

We have investigated the capacity of a range of structurally-diverse, photoactive rhenium(i) tricarbonyl complexes featuring either tetrazolato or N-heterocyclic carbene (NHC) ligands to facilitate fundamental classes of visible-light-mediated photoredox-catalysed reactions. In this study, we demonstrate that these systems mediate representative atom-transfer radical addition, hydrodehalogenation, and alpha-amino C-H functionalisation reactions. These rhenium(i) complexes provide greater or at least comparable reactivity to the prototypical photoredox catalyst [Ru(bpy)3]2+ in many cases.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Synthetic Route of 3340-78-1, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 3340-78-1, 2-Phenyl-1,2,3,4-tetrahydroisoquinoline, introducing its new discovery.

Donor-acceptor type [4+3] covalent organic frameworks: sub-stoichiometric synthesis and photocatalytic application

Three unprecedented 2D [4+3] covalent organic frameworks (TTCOF-1, TTCOF-2, and TTCOF-3) have been prepared by substoichiometric condensation of tetratopic and tritopic monomers, overcoming the limitations of the design rules of conventional topologies. By reticulating the tetraphenylethylene (TPE)-based and triazine-based moieties into COF frameworks, novel electron donor-acceptor (D-A) type structures were obtained. These TTCOFs have good photocatalytic activity in aerobic C(sp3)-H bond functionalization and arylboronic acid oxidation driven by visible light, with yields up to 94%. This can expedite possibilities of COFs with new structural and topological complexities and can also expand the application of COF-based photocatalysis in synthetic chemistry.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Magnetically recoverable iron nanoparticle catalyzed cross-dehydrogenative coupling (CDC) between two Csp3-H bonds using molecular oxygen

The oxidative C-C bond formations between Csp3-H bond adjacent to nitrogen and Csp3-H bond of nitroalkanes are catalyzed efficiently by magnetically recoverable iron nanoparticles using oxygen. The catalyst can be magnetically removed and recycled easily for nine times without decreasing activity. Georg Thieme Verlag Stuttgart.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Visible light catalyzed Mannich reaction between: Tert -amines and silyl diazoenolates

The present work documents the alpha-C-H functionalization of tertiary amines via the visible light catalyzed Mannich reaction with silyl diazoenolates. The reaction takes place at room temperature with an organic dye, Rose Bengal, as a photocatalyst and oxygen as the oxidant. The resulting multifunctional products bearing an alpha-diazo-beta-keto group undergo Rh-carbenoid mediated cyclization, affording stable ammonium ylides in high yields.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 3340-78-1, name is 2-Phenyl-1,2,3,4-tetrahydroisoquinoline, introducing its new discovery. Application In Synthesis of 2-Phenyl-1,2,3,4-tetrahydroisoquinoline

Mechanistic studies on a Cu-catalyzed aerobic oxidative coupling reaction with N-phenyl tetrahydroisoquinoline: Structure of intermediates and the role of methanol as a solvent

The mechanism of an aerobic copper-catalyzed oxidative coupling reaction with N-phenyl tetrahydroisoquinoline was investigated. The oxidized species formed from the reaction of the amine with the copper catalyst were analyzed by NMR-spectroscopy. An iminium dichlorocuprate was found to be the reactive intermediate and could be structurally characterized by X-ray crystallography. The effect of methanol to effectively stabilize the iminium ion was investigated and shown to be beneficial in an oxidative allylation reaction.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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Continuous flow organocatalytic C-H functionalization and cross-dehydrogenative coupling reactions: Visible light organophotocatalysis for multicomponent reactions and C-C, C-P bond formations

A continuous flow procedure for the efficient metal-free, visible light photoredox-catalyzed alpha-functionalization of tertiary amines has been developed. Rose Bengal has been identified as an effective organic photocatalyst for continuous flow C-C and C-P bond formations as well as multicomponent reactions.

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem

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We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 3340-78-1, and how the biochemistry of the body works.Application of 3340-78-1

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A scalable, efficient gold-catalyzed oxidative phosphonation of sp 3 C-H bonds using air as sustainable oxidant

A scalable, efficient gold-catalyzed oxidative phosphonation of sp 3 C-H bonds with various diarylphosphine oxides and dialkyl phosphites has been developed by using air as a sustainable oxidant under mild reaction conditions. It provides an easy access to alpha-amino phosphonic compounds in high yields with a broad reaction scope. The safe, convenient and environmentally benign process makes this protocol very promising. Copyright

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Reference£º
Tetrahydroisoquinoline – Wikipedia,
1,2,3,4-Tetrahydroisoquinoline | C9H11N – PubChem